Zr-MOFs loaded on polyurethane foam by polydopamine for enhanced dye adsorption

Zirconium-based metal-organic frameworks (Zr-MOFs) have attracted widespread attention due to their high specific surface area, high porosity, abundant metal active sites and excellent hydrothermal stability. However, Zr-MOFs materials are mostly powdery in nature and thus difficult to separate from aqueous media, which limits their application in wastewater treatment. In this study, PDA/Zr-MOFs/PU foam was constructed by growing Zr-MOFs nanoparticles on a dopamine-modified polyurethane foam substrate by in-situ hydrothermal synthesis as an adsorbent for removing dyes from wastewater. The results demonstrated that the polydopamine coating improves the dispersion of the Zr-MOFs nanoparticles on the substrate and enhances the interaction between the Zr-MOFs nanoparticles and the PU foam substrate. As a result, compared with Zr-MOFs/PU foam, the prepared PDA/Zr-MOFs/PU foam exhibits higher adsorption capacity for crystal violet (CV) (63.38 mg/g) and rhodamine B (RB) (67.73 mg/g), with maximum adsorption efficiencies of CV and RB of 98.4% (pH=11) and 93.5% (pH=7), respectively, at a concentration of 10 mg/L. The PDA/Zr-MOFs/PU foam can simultaneously remove CV and RB from the mixed solution. Moreover, the PDA/Zr-MOFs/PU foam still exhibits high stability and reusability after five cycles.     

金属有机骨架MIL-68(Al)对水中典型荧光增白剂VBL的吸附去除

以金属有机骨架材料MIL-68(Al)为吸附剂,探究其对水中典型荧光增白剂VBL分子的吸附行为.采用粉末X射线衍射仪(XRD)、傅里叶变换红外光谱(FTIR)、场发射扫描电镜(SEM)及N_2吸附脱附对MIL-68(Al)的结构性质进行表征.探讨了p H值、离子强度、污染物初始浓度、反应温度及吸附时间对MIL-68(Al)吸附去除水中VBL的影响,并对吸附等温线、动力学、热力学及吸附机制进行了分析.实验结果表明,MIL-68(Al)对VBL的吸附能适应较宽的p H范围,吸附等温线符合Langmuir模型,最大吸附容量达到400.02 mg·g~(-1);吸附速率在前20 min很快,并且能在180 min达到吸附平衡,吸附动力学符合准二级动力学模型;吸附过程是吸热反应,吸附自发进行并且主要由熵驱动;静电作用和氢键作用对吸附均有贡献,静电作用是吸附发生的主要机制.由以上结果可知,MIL-68(Al)是一种潜在的高效吸附剂,在去除水中的VBL分子方面极具潜力.     

“十三五”环境经济政策建设规划中期评估研究

《"十三五"全国环境保护法规和环境经济政策建设规划》（以下简称《规划》）绘制了"十三五"时期我国环境保护法规和环境经济政策的创新与改革蓝图。"十三五"以来，《规划》实施推动了环境经济政策在生态文明建设生态环境保护工作中的地位快速上升，在筹集环保资金、调控环境行为、激励企业减排等方面发挥了重要作用。为了更好推进环境经济政策改革与创新，本研究采用逻辑框架法对《规划》中期实施进展进行了系统评价，结果表明：在28项《规划》任务中，绿色信贷、环境信息披露制度、环境污染强制责任险等13项任务进展良好，生态环境损害赔偿制度等11项任务进展较好；环境信用建设"入法"等4项规划任务进展较小或者进展一般。研究表明《规划》总体实施顺利，评估工作也为完成2020年《规划》目标提供了重要技术支撑。     

How percentage-protected targets can support positive biodiversity outcomes

Global targets for the percentage area of land protected, such as 30% by 2030, have gained increasing prominence, but both their scientific basis and likely effectiveness have been questioned. As with emissions-reduction targets based on desired climate outcomes, percentage-protected targets combine values and science by estimating the area over which conservation actions are required to help achieve desired biodiversity outcomes. Protected areas are essential for achieving many biodiversity targets, in part because many species are highly sensitive to human-associated disturbance. However, because the contribution of protected areas to biodiversity outcomes is contingent on their location, management, governance, threats, and what occurs across the broader landscape matrix, global percentage-protected targets are unavoidably empirical generalizations of ecological patterns and processes across diverse geographies. Percentage-protected targets are insufficient in isolation but can complement other actions and contribute to biodiversity outcomes within a framework that balances accuracy and pragmatism in a global context characterized by imperfect biodiversity data. Ideally, percentage-protected targets serve as anchors that strengthen comprehensive national biodiversity strategies by communicating the level of ambition necessary to reverse current trends of biodiversity loss. If such targets are to fulfill this role within the complex societal process by which both values and science impel conservation actions, conservation scientists must clearly communicate the nature of the evidence base supporting percentage-protected targets and how protected areas can function within a broader landscape managed for sustainable coexistence between people and nature. A new paradigm for protected and conserved areas recognizes that national coordination, incentives, and monitoring should support rather than undermine diverse locally led conservation initiatives. However, the definition of a conserved area must retain a strong focus on biodiversity to remain consistent with the evidence base from which percentage-protected targets were originally derived.     

基于要素流动的城镇建设用地配置方法框架探讨

现有城镇建设用地配置主要遵循空间开发导向,利用静态数据和用地分配标准、评估及预测模型开展,存在一定的“区域偏好”和“规模求大”现象。在强调生态文明建设和高质量发展的新时期,国土空间规划战略实施要求城镇建设用地配置方法需要及时革新。关注到信息或智能技术深度影响下未来城镇场所空间将转变为流动空间这一必然趋势,不同尺度生产、生活及生态要素时空流动与分配将是城镇建设用地科学配置的关键。因此,利用多源要素流大数据和多学科分析方法,试图从城镇空间发展水平评价、城镇要素流动网络时空模拟与用地分配、城镇要素功能区识别与开发边界划定、城镇建设用地配置效果动态评估4个方面,建立基于要素流动的城镇建设用地配置方法框架。结果表明：（1）城镇空间发展水平评价需要综合考虑城镇对区域现状要素控制、吸引及溢出的能力,并从空间发展规模、活力及品质三个层面构建评价指标体系;（2）在城镇建设用地指标区域分配过程中注重利用网络优化模型和社会网络分析方法刻画区域要素流动规律,并通过时空耦合模型找出不同等级和类型“空间发展水平—要素控制力”组合的城镇;（3）城镇未来扩展方向和边界形态是由内部各类要素流动变化与功能空间布局的供需时空匹配情况决定的,需要利用时空耦合、引力、CA及多智能体等模型识别要素功能影响区和流动偏好;（4）城镇建设用地配置效果评估指标需要体现生态文明、高质量、智慧治理及一体化等未来城镇发展要求和趋势。这些研究结果可以为国土空间规划城镇开发边界划定和实施提供参考。     

碳中和目标下的国土空间格局优化：理论框架与实践策略

国土空间规划是在基础层面引导土地利用、生态保护、产业布局、城乡建设和区域开发的国家基础性、约束性规划。在当前“双碳”战略背景下,将碳中和目标纳入国土空间规划和治理体系,对于从基础层面推动经济社会系统全面低碳转型具有重要意义。本文构建了碳中和目标下国土空间格局优化的理论框架,分析了国土空间格局、人地关系与碳收支的内在关系。从“经济—社会—生态”复合系统的视角探讨了碳中和目标下国土空间格局优化和调控机理;从国土空间碳收支核算体系、面向碳平衡的“双评价”方法、国土空间碳风险监测与评价、碳排放空间约束下的三线划定、碳达峰与产业空间结构调控等方面提出了面向碳中和的国土空间格局优化路径;从差别化的生态碳汇提升方案、符合中国国情的国土空间碳收支核算体系、面向碳中和目标的国土空间规划管控方案、基于生命周期的建设用地碳排放评估、低碳高效的国土空间治理体系、多层次国土空间碳补偿体系构建等方面,提出了碳中和目标下国土空间格局优化的关键领域。     

基于空间信息技术的城市环境时空调控范式研究

城市环境－生态系统是高度复杂的时空复合动力学系统。通过对城市环境问题的空间动力学机制分析后，提出城市环境可持续发展时空调控的层次途径，并构造了融合遥感、地理信息系统等空间信息技术、环境建模技术、决策支持系统、人工智能等技术的城市生态－环境系统时空调控的体系框架，为城市环境管理及环境空间决策提供新的理论范。     

Development of a Methodology for Strategic Environmental Assessment: Application to the Assessment of Golf Course Installation Policy in Taiwan

Some countries, including Taiwan, have adopted strategic environmental assessment (SEA) to assess and modify proposed policies, plans, and programs (PPPs) in the planning phase for pursuing sustainable development. However, there were only some sketchy steps focusing on policy assessment in the system of Taiwan. This study aims to develop a methodology for SEA in Taiwan to enhance the effectiveness associated with PPPs. The proposed methodology comprises an SEA procedure involving PPP management and assessment in various phases, a sustainable assessment framework, and an SEA management system. The SEA procedure is devised based on the theoretical considerations by systems thinking and the regulative requirements in Taiwan. The positive and negative impacts on ecology, society, and economy are simultaneously considered in the planning (including policy generation and evaluation), implementation, and control phases of the procedure. This study used the analytic hierarchy process, Delphi technique, and systems analysis to develop a sustainable assessment framework. An SEA management system was built based on geographic information system software to process spatial, attribute, and satellite image data during the assessment procedure. The proposed methodology was applied in the SEA of golf course installation policy in 2001 as a case study, which was the first SEA in Taiwan. Most of the 82 existing golf courses in 2001 were installed on slope lands and caused a serious ecological impact. Assessment results indicated that 15 future golf courses installed on marginal lands (including buffer zones, remedied lands, and wastelands) were acceptable because the comprehensive environmental (ecological, social, and economic) assessment value was better based on environmental characteristics and management regulations of Taiwan. The SEA procedure in the planning phase for this policy was completed but the implementation phase of this policy was not begun because the related legislation procedure could not be arranged due to a few senators’ resistance. A self-review of the control phase was carried out in 2006 using this methodology. Installation permits for 12 courses on slope lands were terminated after 2001 and then 27 future courses could be installed on marginal lands. The assessment value of this policy using the data on ecological, social, and economic conditions from 2006 was higher than that using the data from 2001. The analytical results illustrate that the proposed methodology can be used to effectively and efficiently assist the related authorities for SEA.     

The governance of ecosystem services in river basins: An approach for structured data representation and analysis

River basins provide a wide range of ecosystem services important for human well-being. Ecosystem functions and their value to humans have been thoroughly studied. However, the role of governance characteristics for the sustainable management of ecosystem services has been largely ignored up to now. To close this gap, this article introduces the latest modifications to a database building on the Management and Transition Framework (MTF) that serve to study the relationship between water governance and management systems and their performance with regard to impacts on ecosystem services. This comprehensive approach facilitates structured data collection and representation in order to analyze single case studies or compare case studies regarding the governance and management of water resources and associated ecosystem services. It allows the user to investigate whether certain water governance characteristics, such as stakeholder involvement or vertical integration of governance levels, are associated with a change in the management of ecosystem services or a measurable change in their state. A simplified case from South Africa shows how the database modifications allow addressing links between governance and management processes on the one side and ecosystem services and the way they are handled on the other side. Applying the MTF database leads to evidence-based insights into best practices as well as failed management approaches and interventions. This in turn provides knowledge that can be transferred from science to practice supporting sustainable governance of ecosystem services.     

省域安全生产应急救援指挥平台框架体系研究

分析省级安全生产应急救援指挥的业务特点,认为它是一个平时模拟演练和事故现场应急指挥并重、平战结合的一体化过程,是一个广域多部门实时动态的联动过程;笔者提出安全生产应急救援的框架体系,并以网络为基础,以信息技术为手段,以智能设备为前端而构建一个实时直观的应急指挥有机体,包括基础支持系统、综合应用系统、数据库系统、移动指挥平台、前端展示系统,以及法律法规等体系、安全保障体系等,同时重点分析其中的网络结构、综合应用系统,以及与其他单位系统的接口。该框架体系通过广东省安全生产监督管理部门的验证,在实践中是可行的。